Bis[N-(3-aminopropyl)propane-1,3-diamine-κ3 N,N′,N′′]cadmium nitrate perchlorate
نویسندگان
چکیده
The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis-(3-amino-prop-yl)-amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis-(3-amino-prop-yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis-(3-amino-prop-yl)amine ligands in a slightly distorted octa-hedral coordination geometry. In the crystal, mol-ecules are held together by an intricate network of N-H⋯O inter-actions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10).
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